Loki informs the Enchantress that Odin wants her to charm Don Blake, gaining the love of Thor by the same occasion, but Blake recognizes her and resists. Realizing she can't compete with Jane Foster, she seeks the help of the Executioner to get rid of the rival. Seeing that he has failed, she turns his limbs to tree stumps. Thor hurls the two villains back to Asgard.
Odin banishes the Enchantress and the Executioner to Earth for attacking his son Thor. Disoriented in this new world, they seek the leadership of Baron Zemo who accepts their offer to help defeat the Avengers. The Enchantress uses a potion to turn Thor against the other Avengers. But when all her efforts fail and her spell over Thor is broken, the Masters of Evil try to fly away in Zemo's ship but Thor entraps it into a space warp.
The Enchantress casts a spell to bring the Masters of Evil back to Earth. They bail Simon Williams out of imprisonment and take him to South America. Baron Zemo submits the criminal to ionic rays that give him super-strength and names him Wonder Man. After gaining the Avengers' trust, Wonder Man lures the heroes to South America where they all get captured. When Zemo prepares to kill the Avengers, Wonder Man suddenly attacks him and frees the Avengers. The Masters of Evil chose to escape again.
A master of time called Immortus appears before the Masters of Evil and offers to join their team. To prove his worth, Baron Zemo asks him to destroy one of the Avengers. While Immortus has taken Captain America to the past, the Masters of Evil attack the Avengers and gain the upper hand until Cap returns victorious with Rick. The Enchantress casts a spell to bring her team back to the moment before they met Immortus, so for anybody else, it is as if nothing ever happened.
The female ally of Arkon enchants the Black Knight who succumbs to her will. She then transports Avengers Mansion into Arkon's Dimension to capture the Avengers. Enchantress later fights and defeats Wanda in the final battle but that dispels the spell on Black Knight and she flees.
At Zemo's order, the Executioner and the Enchantress set the Melter and the Black Knight free so that the Masters of Evil can engage battle with the Avengers. To avoid injuring citizens, Thor uses his hammer to teleport everybody in a neutral place but being immortal, the Executioner and the Enchantress are able to escape.
Sent by Loki, the Executioner and the Enchantress pay a visit to Jane Foster to capture her but Balder has found them. During their battle the Balder, Thor gets to the scene, which convinces the villains to escape.
On Reed Richards and Sue Storm's wedding day, the Enchantress falls under the control of Doctor Doom's Emotion Charger and join forces with an army of super-villains against the Fantastic Four. Seeing Cobra attacking Captain America, she and the Executioner join the fight against the hero. While the battle rages on, Reed Richards uses a machine that transports all their enemies back to the recent past with no memory of what occurred.
The Enchantress observes as Eric Josten enters Zemo's laboratory and seizes the opportunity to make a new ally and uses Zemo's machine to give him the same powers as Wonder Man's. They put in action a series of incidents that make the Avengers look like menaces to society, which forces the authorities to order them to disband. When to agent pretends to be responsible for the heroes' downfall, Power Man retorts that he and his partner were the ones who framed the Avengers. The Enchantress points to his ally that talked too much, and as fate would have it, it turns out that the agent was Captain America in disguise who just recorded the whole confession. Power Man tries to stop the hero from escaping but the other Avengers join the fight, so the Enchantress decides to teleport and leaves her partner behind.
